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The redox-active sulphydryl group of GSH can protect cells from ROS by directly scavenging free radicals and acting as a cofactor for antioxidant enzymes such as glutathione peroxidases (Gpx1p, Gpx2p and Gpx3p)

However, if darkening is velvety in texture, affects skin folds in multiple areas, and has appeared alongside weight gain, it may be a sign of acanthosis nigricans a condition associated with insulin resistance

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