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Boyle's method of isolating phosphorus was more efficient than Brand's: 4NaPO 3 + 2SiO 2 + 10C 2Na 2 SiO 3 + 10CO + P 4 1826/1827 [John Walker, Samuel Jones] Walker serendipitously discovered a friction match made from antimony sulfide, potassium chlorate, gum, and starch, resulting from a dried blob on the end of a stick used to stir a chemical mixture

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