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Glutamate decarboxylase The presence of GABA in the brain and its synthesis by -decarboxylation of glutamate (see Fig.1) was first described by Roberts and Frankel (1950)

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Synthesized by the action of the rate-limiting enzyme -glutamylcysteine synthetase [4750, 107, 108] glutathione uniquely provides a functional cysteinyl moiety that is responsible for many of its diverse properties