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Shigematsu N, Kawashiri T, Kobayashi D, Shimizu S, Mine K, Hiromoto S, Uchida M, Egashira N, Shimazoe T (2020) Neuroprotective effect of alogliptin on oxaliplatin-induced peripheral neuropathy in vivo and in vitro

Reduction of 3-ketosphinganine forms dihydrosphingosine, which is then typically N-acylated by one of six ceramide synthases (CerS1-CerS6) with 1426 carbon saturated or monounsaturated fatty acids, to form dihydroceramides, subsequently dehydrogenated to ceramides by dihydroceramide desaturase [111]

Consequent to its bioinformatic classification as a thioredoxin reductase, GliT has been predicted by many authors to encode disulphide bond formation in gliotoxin and to play a role in gliotoxin biosynthesis [3], [8], [22]