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Nrf2 controls the basal and induced expression of an array of AREdependent genes to sense oxidants and regulates antioxidant defense

GSH has an active thiol group present on the cysteine residue and functions by directly detoxifying reactive oxygen species (ROS) and reactive nitrogen species (RNS) or indirectly via GSH-dependent peroxidase-catalyzed reactions (Cooper et al., 2011)

They work best together rather than as rivals, since glutathione helps recycle vitamin C and keep it active

A negatively charged side chain from DHKs aspartic acid residue replaces glycine or alanine in other variations, which may affect copper binding and cell membrane interactions