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R2 is selected from the group consisting of a hydrogen atom and an alkyl (e.g., C 1 -C 20 ) or aryl (e.g., C 6 -C 9 ) group

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[0028] In some embodiments, the compositions comprise a cannabinoid, cofactor or precursor thereof, and antioxidant, wherein the cannabinoid is CBD and THC, the cofactor or precursor thereof is niacinamide, and the antioxidant is L-ergothioneine