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*alfalfa fields are often heavily fertilized with sulfur and a couple sources showed alfalfa usually had a higher % dry matter sulfur than grass hay - one said .28% for beef cattle, but I cannot find any more elaboration on this in relation to potential thiamine deficiency or specific to goats

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Unlike catalytic detoxification, which requires precise substrate recognition and can generate reactive intermediates, ligand sequestration provides a passive and energetically efficient means of reducing the bioavailability of xenobiotics