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Similarly, rbohF and rbohD/F mutants infected by TuMV had increased activity of GST and GR, strongly downregulated GPXL, and highly reduced levels of lipid peroxidation

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Z is independently selected from the group consisting of one or more amino acid(s), one or more N-substituted amino acid, optionally substituted polyether, C1-C12 alkylene, arylene having 6 to 10 ring atoms, C3-C8 cycloalkylene, heterocycloalkylene having 5 to 10 ring atoms, heteroarylene having 5 to 10 ring atoms, C2-C10 alkenylene, and any combination thereof, said alkylene and alkenylene being optionally interrupted by one or more heteroatom or chemical groups selected from -O-, -S-, -C(O)-, -NR-, -C(O)NR- , -NR-C(O)-, -NR-C(O)-NR-, -NR-C(O)-O-, -O-C(O)NR- and triazole, and said alkylene, arylene, cycloalkylene, heterocycl R, R and R being independently selected from H and Ci-Ce alkyl

Taken together, the NMR and DFT studies show that the 1,6-addition is highly regioselective and only yields a single product