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Figure 1 2.1 The core enzymatic triad: BCAT4, MAM1, and CYP79F1 The commitment of methionine to aliphatic glucosinolate synthesis is driven by three pivotal enzymes, each executing a distinct and non-redundant step in the construction of the glucoraphanin backbone ( Figure 2 )

Mora-Tiscareo, G

Clin Cancer Res 20(21):5558-69, 2014

Glossary 1-NCA 1-nitrosocyclohexylacetate 3-MP 3-mercaptopyruvate 3-MST 3-mercaptopyruvate sulfurtransferase AGEs advanced glycation end products AICAR 5-amino-4-imidazole-carboxamide riboside AMPK adenosine 5-monophosphate (AMP)-activated protein kinase Ang II angiotensin II ARE antioxidant response element ASC apoptosis-associated speck-like protein containing A CARD CASQ2 calsequestrin 2 CAT cysteine aminotransferase CBS cystathionine -synthase CHOP C/EBP-homologous protein CK-MB creatine kinase MB isozyme CO carbon monoxide COX-2 cyclooxygenase-2 CSE cystathionine -lyase DAO d-amino acid oxidase eIF2 eukaryotic initiation factor 2 ERK1/2 extracellular regulated protein kinase 1/2 GAPDH glyceraldehyde-3-phosphate dehydrogenase GRP78 glucose-regulated protein H2S hydrogen sulfide HFD high fat diet HNO nitroxyl HO-1 heme oxygenase 1 Hrd1 HMG-CoA reductase degradation protein IL-1 interleukin 1 iNOS inducible nitric oxide synthase JAK Janus kinase JNK c-Jun N-terminal kinase MAPK mitogen activated protein kinase MLCK myosin light chain kinase MMP-2 matrix metalloprotease 2 mTOR mammalian target of rapamycin MuRF1 muscle RING finger-1 NaHS sodium hydrosulfide NF-B nuclear transcription factor-B NLRP3 nucleotide-binding oligomerization domain-like receptor protein 3 NO nitric oxide NQO1 Nad(p)h: quinone oxidoreductase 1 Nrf2 nuclear factor erythroid 2-related factor 2 PDE5 phosphodiesterase 5 PERK pancreatic endoplasmic reticulum kinase PI3K phosphatidylinositol 3-kinase PKC protein kinase C RAS reninangiotensin system ROS reactive oxygen species RyR2 ryanodine receptor SERCA2a sarcoplasmic reticulum Ca2+ ATPase Smad3 SMAD family member 3 SNP sodium nitroprusside STAT3 signal transducer and activator of transcription 3 STZ streptozotocin TGF-1 transforming growth factor 1 TIMP-2 tissue inhibitor of metalloproteinase 2 TLR4 toll-like receptor 4 USP8 ubiquitin specific peptidase 8 VAMP3 vesicle-associated membrane protein 3 References 1 AbeK.KimuraH