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The sulfidation of AgNPs to the highly insoluble and biologically inert mineral Ag2S, a common process in anoxic sediments, effectively deletes the dominant toxicity pathway for pristine AgNPs by shutting down the release of toxic Ag+ ions.92,93 Similarly, the progressive oxidation of an nZVI particles reactive Fe0 core to a more benign iron (oxy)hydroxide shell concurrently neutralises both its remedial efficacy and its capacity to generate ROS via Fenton chemistry